Pemanfaatan Limbah Tongkol Jagung sebagai Bioadsorben dalam Proses Adsorpsi Besi(II) dan Metilen Biru
DOI:
https://doi.org/10.30872/cmg.v8i1.11152Abstract
Pertumbuhan industri akan menghasilkan efek samping, salah masalahnya adalah pencemaran limbah cair yang mengandung logam berat dan zat warna. Pencemaran tersebut dapat berdampak buruk bagi lingkungan sehingga perlu untuk diolah. Proses pengolahan limbah cair yang dapat dilakukan adalah dengan proses adsorpsi. Adsorpsi menggunakan karbon aktif berbahan dasar tongkol jagung yang sebelumnya dilakukan proses karbonasi pada 350⁰C selama 3 jam. Tongkol jagung yang telah menjadi karbon, dihaluskan hingga ukuran 20, 40, dan 60 mesh. Proses aktivasi dengan larutan ZnCl2 0,3 M. Proses adsorpsi ini berlangsung secara kontinu dengan debit 100 ml/menit. Karbon aktif yang dihasilkan telah memenuhi spesifikasi karbon aktif berdasarkan SNI. Proses adsorpsi secara kontinu ini berhasil menurunkan besi(II) hingga 99,55% dengan ukuran karbon aktif sebesar 40 mesh. Hal serupa juga berhasil dilakukan untuk menurunkan metilen biru hingga 97,565% dengan ukuran karbon aktif sebesar 60 mesh. Nilai penurunan ini dipengaruhi oleh penurunan ukuran partikel yang akan berdampak pada peningkatan besar kapasitas adsorpsi.
References
Alsulaili, A.D., Refaie, A.A., dan Garcia, H.A., (2023) ‘Adsorption Capacity of Activated Carbon Derived from Date Seeds: Characterization, Optimization, Kinetic and Equilibrium Studies’, Chemosphere, 313, pp. 1-10. https://doi.org/10.1016/j.chemosphere.2022.137554.
Bergna, D., Varila, T., Romar, H., dan Lassi, U., (2022) ‘Activated carbon from hydrolysis lignin: Effect of Activation Method on Carbon Properties’, Biomass and Bioenergy, 159, pp. 1-8. https://doi.org/10.1016/j.biombioe.2022.106387.
Bosch, D., Back, J.O., Gurtner, D., Giberti, S., Hofmann, A., dan Bockreis, A., (2022) ‘Alternative Feedstock for the Production of Activated Carbon with ZnCl2: Forestry Residue Biomass and Waste Wood’, Carbon Resources Conversion, 5, pp. 299-309. https://doi.org/10.1016/j.crcon.2022.09.001.
Dada, A.O., Inyinbor, A.A., Tokula, B.E., Bello, O.S., dan Pal, U. (2022) ‘Preparation and characterization of rice husk activated carbon-supported zinc oxide nanocomposite (RHAC-ZnO-NC)’, Heliyon, 8, pp. 1-8. https://doi.org/10.1016/j.heliyon.2022.e10167.
Dimpe, K.M., dan Nomngongo, P.N. (2017) ‘A Review on The Efficacy of The Application of Myriad Carbonaceous Materials for The Removal of Toxic Trace Elements in The Environment’, Trends in Environmental Analytical Chemistry, 16, pp. 24–31. https://doi.org/10.1016/j.teac.2017.10.001.
Erawati, E. dan Fernando, A. (2018) ‘Pengaruh Jenis Aktivator dan Ukuran Karbon Aktif Terhadap Pembuatan Adsorbent dari Serbik Gergaji Kayu Sengon (Paraserianthes Falcataria)’, Jurnal Integrasi Proses, 7, pp. 58-66. http://dx.doi.org/10.36055/jip.v7i2.3808.
Gan, Yong X. (2021) ‘Activated Carbon from Biomass Sustainable Sources’, Journal of Carbon Research, pp. 1-33. https://doi.org/10.3390/c7020039.
Giraldo, S., Robles, I., Godínez, L.A., Acelas, N., dan Flórez, E. (2021) ‘Experimental and Theoretical Insights on Methylene Blue Removal from Wastewater Using an Adsorbent Obtained from the Residues of the Orange Industry,’ Molecules, 26, pp. 1-15. https://doi.org/10.3390/molecules26154555.
He, X., Chen, X., Wang, X., dan Jiang, L. (2023) ‘Optimization of Activated Carbon Production From Corn Cob Using Response Surface Methodology’, Frontier in Enviromental Science, pp. 1-11. doi: 10.3389/fenvs.2023.1105408.
Jawad, A.H., Saud Abdulhameed, A., Wilson, L.D., Syed-Hassan, S.S.A., ALOthman, Z.A., dan Rizwan Khan, M. (2021) ‘High Surface Area and Mesoporous Activated Carbon from KOH-Activated Dragon Fruit Peels for Methylene Blue Dye Adsorption: Optimization and Mechanism Study’, Chinese Journal of Chemical Engineering, 32, pp. 281–290. https://doi.org/10.1016/j.cjche.2020.09.070.
Khalil, K.M.S., Elhamdy, W.A., Mohammed, K.M.H., dan Said, A.E.A.A. (2022) ‘Nanostructured P-doped Activated Carbon with Improved Mesoporous Texture Derived from Biomass for Enhanced Adsorption of Industrial Cationic Dye Contaminants’, Materials Chemistry dan Physics, 282, 125881. https://doi.org/10.1016/j.matchemphys.2022.125881
Makhwedzha, R.D., Mavhungu, A., Moropeng, M.L., dan Mbaya, R. (2022) ‘Activated carbon derived from waste orange and lemon peels for the adsorption of methyl orange and methylene blue dyes from wastewater’, Heliyon, 8, pp. 1-9. https://doi.org/10.1016/j.heliyon.2022.e09930.
Maulina S., Iriansyah, M. (2018) ‘Characteristics of activated carbon resulted from pyrolysis of the oil palm fronds powder’, IOP Conf. Series: Materials Science and Engineering, 309, pp. 1-7. 10.1088/1757-899X/309/1/012072.
Maryudi, M., Amelia, S., dan Salamah, S. (2019) ‘Removal of Methylene Blue of Textile Industry Waste with Activated Carbon using Adsorption Method’, Reaktor, 19, pp. 168-171. https://doi.org/10.14710/reaktor.19.4.168-171
Musthofa, A.M.H., Syafila, M., dan Helmy, Q. (2023) ‘Effect of Activated Carbon Particle Size on Methylene Blue Adsorption Process in Textile Wastewater’, Indonesian Journal of Chemistry, 23, pp. 461-474. https://doi.org/10.22146/ijc.79784.
Pan, L., Nishimura, Y., Takaesu, H., Matsui, Y., Matsushita, T., dan Shirasaki, N. (2017) ‘Effects of Decreasing Activated Carbon Particle Diameter from 30 μm to 140 nm on Equilibrium Adsorption Capacity, Water Research, 124, pp. 425-434. https://doi.org/10.1016/j.watres.2017.07.075.
Prasad, A.L., Santhi, T., Manonmani, S. (2015) ‘Recent developments in preparation of activated carbons by microwave: Study of residual errors’, Arabian Journal of Chemistry, 8, pp. 343-354. https://doi.org/10.1016/j.arabjc.2011.01.020.
Pusat Data dan Sistem Informasi Pertaniann Kementrian Pertanian. (2020). Outlook Jagung. Jakarta: Kementrian Pertanian.
Shamsuddin, M.S., Yusoff, N.R.N., Sulaiman, M.A. (2016) ‘Synthesis and Characterization of Activated Carbon Produced from Kenaf Core Fiber Using H3PO4 Activation’, Procedia Chemistry, 19, pp. 558-565, https://doi.org/10.1016/j.proche.2016.03.053.
Takaesu, H., Matsui, Y., Nishimura, Y., Matsushita, T., dan Shirasaki, N. (2019) ‘Micro-milling super-fine powdered activated carbon decreases Adsorption capacity by Introducing Oxygen/hydrogen-containing Functional Groups on Carbon Surface from Water’, Water Research, 155, pp. 66-75. https://doi.org/10.1016/j.watres.2019.02.019.
Wang, B., Lan, J., Bo, C., Gong, B., dan Ou, J. (2023)’ Adsorption of heavy metal onto biomass-derived activated carbon: review’, RSC Advances, 13, pp. 4275–4302. 10.1039/d2ra07911a.
Zega, F.I., Selly, R., dan Zubir, M. (2021) ‘Review of Adsorption of Fe Metal by Activated Carbon Adsorbent’, Indonesian Journal of Chemical Science and Technology, 4, pp. 74-78. https://doi.org/10.24114/ijcst.v4i2.27600.
Downloads
Published
Issue
Section
License
Licensed Use of Non - Commercial Articles will be governed by the Creative Commons Attribution license, which is featured on the Creative Commons Attribution 4.0 International License.
The author guarantees that the articles published through JURNAL CHEMURGY are original and do not contain statements that violate the law do not violate others' rights are subject to copyright, which is held exclusively by the author and free from the rights of third parties. The author is allowed to quote from various sources used for research and not to harm any party.
JURNAL CHEMURGY disseminates articles published with the rules set by Creative Commons. JURNAL CHEMURGY license allows users to copy, distribute, display, and work for non-commercial purposes. Users also need to connect authors and JURNAL CHEMURGY with the distribution of articles in journals.
The Author rights, namely copyrights, ownership rights, patents, rights to use the substance of articles in the future, rights to reproduce articles for personal purposes and not to be traded, rights to conduct personal archives, rights to contract used for the non-exclusive distribution of articles published in the form a book and acknowledge the initial publication of the article originating from JURNAL CHEMURGY.
Suppose articles published by the author through JURNAL CHEMURGY are compiled with other authors. In that case, it is necessary to create a form containing the authority of all authors involved in the article's production by including the agreement agreed upon by all authors in the article.
The next point is, the agreement can be terminated if the author or JURNAL CHEMURGY violates the agreement and cannot make repairs to the customer within a maximum of 2 months after being given information asking for the violation to be corrected. If there is no violation of the agreement, the license will automatically terminate and affect JURNAL CHEMURGY.
Regarding royalties, so far, if it is following applicable legal regulations, the author will waive his right to collect royalties on articles that have been licensed by JURNAL CHEMURGY.
In publishing the article, the editorial process is successful. JURNAL CHEMURGY will continue it. JURNAL CHEMURGY has the right to adjust articles related to punctuation, spelling, capital letters, references used, and usage adapted to JURNAL CHEMURGY. The author acknowledges that the article can be published and accessed free of charge by the public.